2/29/2024 0 Comments Green steve minecraft seed![]() However, the seed world in which the Herobrine hoax started is, in fact, real. There was never a character like this in Minecraft, as explained by a moderator on Reddit: "Note that Herobrine is not real and has never been, this is just the seed used for the original creepypasta image." Read more: Who is Dream? The story of Minecraft's unseen YouTuberĪgain, Herobrine isn't real.It was also rumoured that Herobrine was a tribute to Minecraft creator Markus "Notch" Persson's deceased brother. (Picture: Glitchunpatched via Minecraft Gamepedia)įor those who are unaware, Herobrine looks like the default player skin, with ghost-white eyes, and exhibiting odd behaviour like digging 2x2 holes. ![]() The seed was discovered on January 16 by andrew555 (Kminster), who said on Reddit that it took. The SCARIEST Seed to Find GREEN STEVE in Minecraft (Scary World) SIMPLE 1. Herobrine became somewhat of Minecraft's version of Slenderman, with some players creating hoax images claiming to have spotted him. And now, as detailed at MinecraftHome, the original Herobrine seed has been discovered as well. ![]() ![]() He is a myth first made the rounds on Creepypasta back in 2010. Bedrock is designed to run smoothly on all kinds of computers, and it. There’s simply more content out there about Bedrock - because it’s, in a few words, more popular. This world was generated in 1.4.4.8.1 with the seed 1.95035. Who is Minecraft's Herobrine?įirst of all, the creepy character Herobrine is Minecraft folklore. Top 15 Minecraft Best Java Seeds That Are Fun It can often be difficult to find good world seeds for Minecraft’s Java Edition. The game will first try to generate in the green zone, then the yellow zone if that fails. Now, another iconic secret has been found in the Herobrine seed world, and in this article, we will tell you how to join it. Ich entdecke die Höhle von Green Steve und andere gru. Never thought I'd say this, but you can now find desert wells on Chunk Base.In July 2020 the seed for Minecraft's title screen world was finally found, followed by the seed for Minecraft's famous pack.png world in September. In diesem Minecraft Video erkunde ich den verfluchten Minecraft Seed, in dem Green Steve lauern soll.You can now find trail ruins on /apps/seed-map Mar 24, 2023.Just made 1.20 the default version on Chunk Base in preparation of tomorrows release.What is green Steves code fot Minecraft, Minecraft Questions and answers, PC. Please do not use this box to ask a question, it will be rejected - this box is for answers ONLY. For more questions for Minecraft check out the question page where you can search or ask your own question. Answers that are too short or not descriptive are usually rejected. At coordinates X: 285 Z: 85 you’ll see ocean ruins glitching right into an exposed ruined portal That’s it for this month’s best Minecraft 1.20.3 seeds for November 2023. I did not make the worldedit mod, the developers of that are sk89q & wizjany. The invisible items that say water, packed ice, and lava need worldedit. Please be as detailed as you can when making an answer. If you ever wanted to see the drowned making an attempt at traveling into the nether, then here’s your chance. If you want the steves in Minecraft you might want this mod. Couldn't migrate all data though (users, likes, reactions) Jul 6, 2023 What is the seed for green Steve Xbox one. THE MOST CREEPY GREEN STEVE SEED For Minecraft Xbox 360, Minecraft Xbox One and Minecraft Wii U. This should help with performance, privacy and get rid of the malicious ad redirects some of you have run into. ![]() As always, combine with underground biomes to find lush or dripstone variants! Thanks to Jereaux for the suggestion and help :) Sep 12, 2023 Added a new cheese cave size (huge) which is also marked with a star icon on the map.Some UI updates for a change: Double click/tap to make the map bigger, "R" key to randomize the seed Oct 31, 2023.Added Java 1.21 experimental with trial chambers on /apps/seed-map. THE MOST CREEPY GREEN STEVE SEED (Ps3/Xbox360/PS4/XboxOne/WiiU) Drewsmc 3.4M subscribers Subscribe 1.1K 79K views 5 years ago THE MOST CREEPY GREEN STEVE SEED For Minecraft Xbox 360.On the front side of things, it dons beautiful greenery with lush trees and a river flowing through the land. This Minecraft seed features beautiful icy plains in the distance with a rocky terrain. Trial chambers are now available for Bedrock, too! Nov 16, 2023 Some seeds may vary between different versions of Minecraft.Note that the completion data is only stored locally on your device for now. When clicking on an icon, you can now mark it as complete and copy the /tp command to the clipboard. ![]()
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2/29/2024 0 Comments Mac os mojave boot camp![]() ![]() Īll but abandoning the idea of an operating system, NeXT managed to maintain a business selling WebObjects and consulting services, only ever making modest profits in its last few quarters as an independent company. It also supported the innovative Enterprise Objects Framework database access layer and WebObjects application server development environment, among other notable features. This environment is known today in the Mac world as Cocoa. ![]() It featured an object-oriented programming framework based on the Objective-C language. NeXTSTEP was based on the Mach kernel developed at CMU (Carnegie Mellon University) and BSD, an implementation of Unix dating back to the 1970s. The hardware was phased out in 1993 however, the company's object-oriented operating system NeXTSTEP had a more lasting legacy as it eventually became the basis for Mac OS X. As the first workstation to include a digital signal processor (DSP) and a high-capacity optical disc drive, NeXT hardware was advanced for its time, but was expensive relative to the rapidly commoditizing workstation market. The current major version, macOS 14 Sonoma, was announced on Jat WWDC 2023 and released on September 26 of that year.ĭevelopment Development outside Apple A diagram of the relationships between Unix systems including the ancestors of macOSĪfter Apple removed Steve Jobs from management in 1985, he left the company and attempted to create the "next big thing", with funding from Ross Perot and himself. Starting with Mac OS X 10.2 Jaguar, big cat names were used as marketing names starting with OS X 10.9 Mavericks, names of locations in California were used as marketing names instead. Mac OS X 10.0 and 10.1 were given names of big cats as internal code names ("Cheetah" and "Puma"). MacOS retained the major version number 10 throughout its development history until the release of macOS 11 Big Sur in 2020. The operating system was further renamed to "macOS" starting with macOS Sierra.įrom the introduction of machines not supporting the classic Mac OS in 2003 until the introduction of iPhone OS in early 2007, Mac OS X was Apple's only software platform. ![]() Lion was referred to by Apple as "Mac OS X Lion" and sometimes as "OS X Lion" Mountain Lion was officially referred to as just "OS X Mountain Lion", with the "Mac" being completely dropped. Starting with the Intel build of Mac OS X 10.5 Leopard, most releases have been certified as Unix systems conforming to the Single UNIX Specification. The macOS Server app was discontinued on Apand will stop working on macOS 13 Ventura or later. Starting with Mac OS X 10.7 Lion, macOS Server is no longer offered as a standalone operating system instead, server management tools are available for purchase as an add-on. Since then, several more distinct desktop and server editions of macOS have been released. The desktop version aimed at regular users- Mac OS X 10.0-shipped in March 2001. It was built using the technologies Apple acquired from NeXT, but did not include the signature Aqua user interface (UI). MacOS was first released in 1999 as Mac OS X Server 1.0. To ease the transition for users and developers, versions through 10.4 were able to run Mac OS 9 and its applications in the Classic Environment, a compatibility layer. The transition was a technologically and strategically significant one. Īlthough it was originally marketed as simply "version 10" of Mac OS (indicated by the Roman numeral "X"), it has a completely different codebase from Mac OS 9, as well as substantial changes to its user interface. ![]() However, the current macOS is a UNIX operating system built on technology that had been developed at NeXT from the 1980s until Apple purchased the company in early 1997. That system, up to and including its final release Mac OS 9, was a direct descendant of the operating system Apple had used in its Mac computers since their introduction in 1984. The history of macOS, Apple's current Mac operating system formerly named Mac OS X until 2011 and then OS X until 2016, began with the company's project to replace its "classic" Mac OS. ![]() 2/29/2024 0 Comments Mobile homes like log cabins![]() ![]() Purchasing a Modular Log Home NC is generally more cost effective than constructing a log home on-site. We’ve removed most of the variables in the log home building process normally associated with site-built Log Cabin Kits and eliminated the complications that arise from on-site log home construction. It’s a extraordinary building method, and it’s why Mountain Recreation Log Cabins is a leader in the log home industry. You will receive all the rustic charm you would expect from a traditional log home, but with the precision, efficiency, and speed that comes with the modular building process. MRLC builds authentic, solid log homes, in a factory-controlled process. Whether you own a campground and are looking for more rental options, or you’re looking for a mountain recreation getaway cabin, we have plans to fit about any budget. They can be used as a summer lakeside retreat, fall leaf watching getaway, family vacation destination or desirable romantic hideaway. Log Cabins create the possibility of a year-round revenue stream. Each cabin plan can be customized with the options you desire. Our custom designed log cabins are affordable and come in many sizes, prices and floor plans. ![]() Looking for a rental property investment sure to keep customers coming back year after year? Our Modular Log Cabin floor plans allow for one or two bedrooms with plenty of space for everyone to have a great time. 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Our Modular Log Cabins come in a variety of sizes and with endless options for customization. ![]() 2/29/2024 0 Comments Numerology calculation![]() ![]() For example, if you were born in 2001, add together 2+0+0+13. Then add together the digits of that number: 2+24. If you were born in 1957, add together 1+9+5+722. In some scenarios, the final life path number will be the same when calculated correctly and incorrectly. Numerology Calculation a poster with handwritten instructions for how to. If you have noticed, the calculation of the year is reduced to one digit before you add it to the Day and Month numbers. txt file is free by clicking on the export iconĬite as source (bibliography): Chaldean Numerology on dCode. Reduce the year of your birth to a single number. the numerology worksheet is shown in black and white. Our free Numerology Chart summary includes the calculation methods and short introduction to your Life Path number, Expression number, Hearts Desire number. ![]() Determine your Lucky number using this lucky number. The copy-paste of the page "Chaldean Numerology" or any of its results, is allowed (even for commercial purposes) as long as you cite dCode!Įxporting results as a. Lucky Number in Numerology is calculated based on your date of birth and the numerology number of your name. This is pretty straightforward so far, but there is one. Your FREE numerology calculator reading The first and last name you use each day give your full numerology name reading. Then keep adding until you get a single digit: In this case, 3+1 a life-path number of 4. For example, if your birthday is November 2, 1998, or, you would add 1+1+2+1+9+9+8 31. ![]() Except explicit open source licence (indicated Creative Commons / free), the "Chaldean Numerology" algorithm, the applet or snippet (converter, solver, encryption / decryption, encoding / decoding, ciphering / deciphering, breaker, translator), or the "Chaldean Numerology" functions (calculate, convert, solve, decrypt / encrypt, decipher / cipher, decode / encode, translate) written in any informatic language (Python, Java, PHP, C#, Javascript, Matlab, etc.) and all data download, script, or API access for "Chaldean Numerology" are not public, same for offline use on PC, mobile, tablet, iPhone or Android app! How do I calculate my life-path number Write out your birthday in digits and then add them all up. Ask a new question Source codeĭCode retains ownership of the "Chaldean Numerology" source code. Chaldea is the name given to a region of Mesopotamia (between Iraq and Iran) located between the Euphrates and Tigris rivers. ![]() 2/29/2024 0 Comments Convert youtube to mpg![]() Our search does not find playlists as results, so you will need to actually copy Youtube playlist URL from the app or internet browser. YConverter also supports Youtube playlist downloads. Wait for search results and now pick out whatever video you like and start Youtube converter. Pick one or finish typing yours and submit. Simply type in some words, maybe even start with 1-2 letters, and we will offer some local popular search tags. We value your time and have thus created our own Youtube search mechanism, so you can use input box above as search box. Using our website you don't need to leave here, go to Youtube and try to find next video you want to download. YConverter is proud to show off built-in Youtube video search. Step 4 Start to download YouTube to MPEGĬlick "RUN" button and the YouTube movie converter will automatically start to download and convert YouTube to MPEG.Advanced Youtube search & playlist support Step 3 Select the output folderĬlick the "Browse" button and choose the location where you would like to download YouTube to mpeg into. Besides, rich portable device profiles are also available, from which you can convert YouTube to iPhone, iPad, Samsung, Kindle Fire, HTC One, Xbox etc. Note: In addition to download YouTube flv to MPEG, this YouTube MPEG converter can convert YouTube to other video formats, like convert YouTube video to MP4, MOV, FLV, AVI, WMV etc. ![]() ![]() To convert YouTube to MPEG, choose MPEG as the output format from the format list. Step 2 Choose "to MPEG" as the output format Or clicking "paste & analyze" button to automatically detect the YouTube videos on the opening website page. Hit "YouTube" button and click "analyze" to load the YouTube video you want to convert from FLV to MPEG by copying and pasting the wanted video URL from YouTube. How to Convert YouTube to MPEG on Mac with High Quality Step 1 Load YouTube videoĭownload YouTube to MPEG converter for Mac. MPEG provides possibility of creating new encoder concept based on MPEG. MPEG offers large variety of simple inexpensive decoders. MPEG is a cross-platform and non-commercial standard. MPEG delivers high video quality while stay with small file size, which means you can store more videos in your devices. MPEG is supported by all popular web browsers, many popular media players, like Windows Media Player, Apple QuickTime Player and other movie players and operating systems such as Windows, Mac OS X, Symbian OS, Android and more. Why so many people look for how to convert YouTube FLV to MPEG, check the benefits the format MPEG can bring below: If it's unfortunately not included in formats for certain devices, it's easy to convert YouTube or other videos to MPEG with a reliable YouTube MPEG converter. As one of the most most popular formats that allows streaming high quality video on the internet, to download videos from YouTube to MPEG means you can enjoy enjoy the downloaded videos on extensive devices as well as players: These files can be played with Windows Media Player, Apple QuickTime Player, Cyberlink PowerDVD, Xine Player and other multimedia players MPEG is included in lists of supported files of most devices, like the iPhone supported formats, iPad Air formats etc. Why we need to convert YouTube to MPEG? The common-used standards are MPEG-1(.MPG), MPEG-2(.MPG) and MPEG-4(.MP4). And that's a major reason that users need a YouTube mpeg converter. For this reason, many users want to get the online Web, music videos, movie trailers and other video clips from YouTube download and convert to MPEG format to keep high quality and small size. Even after being compressed with a YouTube to MPEG converter, MPEG files will stay almost the same original quality of the uncompressed movie. ![]() The term stands for the family of digital video and audio compression standards and file formats formulated by the group. MPEG is short for Moving Picture Experts Group, a working group of ISO that was established in 1988. Before we download YouTube to MPEG with a YouTube MPEG convreter, let's look at why MPEG format is and will always be among the top choices when users want to download YouTube videos. Time and again questions on how to download and convert YouTube videos to MPEG will pop up. Why Do People Need to Convert YouTube to MPEG ![]() 2/29/2024 0 Comments Best gpu benchmark test![]() ![]() #10 got benchmark programm data, about to get FAL images +0.01s. ![]() #8 Created sortOrder for cached benchmark data +0s. #7 Loaded cached benchmark data tx_nbc2_gpu_cache_values +0s. #6 found 2366 cached benchmark values +0.02s. #4 Cache table found with all needed fields in it! +0s. #3 Cache table for values found, checking fields. Memory DirectX OpenGL Process (nm) Days old all, noneģDMark Ice Storm GPU 3DMark Cloud Gate Standard Score 3DMark Cloud Gate GPU 3DMark11 P 3DMark11 P GPU 3DMark Fire Strike Score 3DMark Fire Strike Graphics 3DMark Time Spy Score 3DMark Time Spy Graphics 3DMark Vantage P 3DMark06 3DMark01 GFXBench GFXBench 3.0 1080p Manhattan Offscreen GFXBench 3.1 Manhattan ES 3.1 Offscreen Basemark GPU 1.2 Vulkan Medium Offscreen Basemark X 1.1 Medium Quality Basemark X 1.1 High Quality Unigine Heaven 3.0 DX 11, Normal Tessellation, High Shaders Unigine Valley 1.0 Extreme HD DirectX Cinebench R15 OpenGL 64Bit Cinebench R10 32Bit OpenGL ComputeMark v2.1 Normal, Score LuxMark v2.0 64Bit Sala GPUs-only all, none ![]() Developed by Kishonti Ltd. Model Codename Architecture Pixel Shaders Vertex Shaders Core speed Shader Speed Boost / Turbo Memory Speed Memory Bus Memory Type Max. Cross-Platform, Graphics Benchmark Tool for PC and Mobile Devices (Free) GFXBench is a high-powered, cross-platform graphics benchmarking tool designed to measure the capabilities and performance of your PC and mobile devices GPU. (Manufacturer, Model, Series, Codename), Connect search words with and or .Īnnounced at least months ago (>0) Show only items with known benchmark results Still available (not archived) Show benchmark bars Show single scores on hover Show Percent Show performance classes Perf. ![]() 2/29/2024 0 Comments Play bejeweled 2 online for free![]() ![]() However, Kizi’s unblocked games are always available for you to enjoy. BEJEWELED 2 The sequel to the classic puzzle game. If you’re using wifi, you might encounter public networks at school, in the library, or around town that block gaming content. There are lots of amazing Bejeweled variations to discover, each with their own special tips and tricks, so have a browse and find your favourite editions! To enjoy even more of our entertaining games, check our catalogue of fun and challenging puzzles! Awesome Bejeweled games unblockedĮxperience the best online Bejeweled games wherever you go, on laptop computer, tablet, and you mobile phone. In Quest mode, the shape of the board often changes, making the game more challenging. Objectives might include clearing away frozen cells, or dropping certain items to the bottom of the board to collect them. Learn more about the history and hints of bejewled 2, we also have diamond mine bejewelled and bejeweld to play. Free Bejeweled Online aka diamond mine with high-scores. In Quest mode, you have to solve the different levels within a certain amount of moves or time. Match three or more jewels in a row to get points. Some versions also feature a Zen mode, a relaxing version in which there is no time limit at all. The objective is to score as many points as possible. Keep playing for as long as you can! In Lightning Rounds, the amount of time is fixed. In most cases, you’ll be able to add extra time to the clock by creating lots of matches. In time trial mode, you have to make as many combinations as possible before your time runs out. The available modes depend on the title you choose. You can play Bejeweled in lots of different game modes. ![]() Match the gems in the different Bejeweled online game modes A cascade is a chain reaction where the new gems that fall into place also form gem combos. You can boost your score and earn bonus items such as bombs by creating a cascade. The gems above will fall down to fill the gaps, and new gems will tumble into the grid from the top. When you make a combination, the gems will pop and vanish from the board. You can only swap two gems if they are placed directly next to one another, and a swap is only valid if it results in an instant match. Since then, a great number of new titles has been released, and we’ve collected the best ones here for you! The game consists of a grid filled with brightly colored gems, and the player’s objective is to swap the gems around to make combinations of three or more identical ones. Play the best Bejeweled games for free at Kizi!īejeweled tile-matching games have been available online since 2001, which marked the launch of PopCap’s popular original title. ![]() 2/28/2024 0 Comments Predator vs prey scholastic ebook![]() ![]() If the predator and prey populations are balanced, they will go up and down over time, chasing each other in the circle of life. When the lynx population decreases, the hare population increases again, and the up-down cycle continues. When the hare population is low, this means less food for the lynxes and results in a decrease in the lynx population. In Figure 1, can you see that the populations of lynxes and hares fall and rise at around the same time? When there are more lynxes they eat more hares, which decreases the hare population. The rise and fall in the recorded hare and lynx populations over time suggests that there is a relationship between the two animals, which makes sense as we know that lynxes eat hares. (B) The number of lynx pelts collected (in tens of thousands) over time, inferred from Hudson Bay Company data from 1895 to 1935 1.Figure 1 - (A) The number of hare pelts collected (in tens of thousands) over time.The data show that in some years, like 1927, there were more lynxes (predators) but fewer hares (prey), while in other years, like 1932, there were more hares but fewer lynxes. The number of hare or lynx pelts collected tells us about the levels of each animals’ population and can give us a reasonable picture of the predator-prey relationship. Figure 1 shows the company’s data for the number of hare and lynx pelts. The Hudson Bay Company made yearly records of the numbers of snow lynx and snowshoe hare pelts they collected. To model a predator-prey relationship, we will use population data (records of how many animals there are) collected by a company that hunted both the predators and prey for their fur in the nineteenth and twentieth centuries. In this paper we will show how some basic mathematics, like addition, subtraction, and multiplication, can be used to model the predator-prey relationships seen in the wild. To make a successful mathematical model, we need to collect data from the environment. Modelling the relationship between predators and prey helps scientists understand how their populations change over time, and it can let scientists know when an animal could be at risk of extinction. Scientists sometimes use mathematics to test theories they have about the animals or even to try to predict the future! This is called mathematical modelling. Scientists need to collect information so they can understand how to protect the environment and the animals who live there. In this article, we show what the predator-prey relationship looks like over time and explain how scientists can make predictions about future population levels, all using basic mathematics like addition, subtraction, and multiplication. What do you think would happen if a predator were introduced to an ecosystem where the prey previously lived without fear of being hunted? Would the new predator eat all the prey animals until they go extinct? Actually, the relationship between predator and prey is far more interesting than this. ![]() Animals who are hunted and eaten are known as prey. Some animals hunt other animals to feed themselves these animals are called predators. ![]() 2/28/2024 0 Comments Gmc iridium metallic paint![]() All orders are direct shipped from the manufacturer. Please allow up to 30 days to ship. Touch-Up Paint General Motors Perfect Match Iridium Metallic (GXG WA121V) Dupli-Color Scratch-Fix All n 1 Premium Automotive Paint is an easy-to-use, high-quality, fast-drying, acrylic lacquer aerosol paint specially formulated to exactly match the color of the original factory applied coating.Other common color promotional names include Tungsten and Dark Granite. This two-step paint system consists of step one, the. Why The Two-Step Paint System Your 2016 GMC Acadia is painted at the factory with a high quality basecoat/clearcoat system. The 2024 GMC Acadia Will Offer Three New Paint Colors Larger 2024 GMC Acadia Creates Space For Axed GMC Jimmy. Try searching other GMC Sierra years or Submit a color request. Paint code GM wa121v - gray : This gray automotive paint color is most commonly known as Iridium. Iridium Metallic: 140X, G1W, WA140X: Abalone White Pearl: 143X, G7U, WA143X: Plum Berry Metallic: 17, 17U, 636R, 8636, GAN, WA636R: Switchblade Silver Metallic. Iridium Metallic 1: GXG: WA-121V: A: A: A: A: A: Legend: A Available. Additional GMC paint colors may be available, especially interior, trim and wheel colors. Show 31 other colors for 2015 GMC Sierra. Genuine GM OEM Tungsten Metallic/Iridium Paint (GXG) Iridium Gray Metallic Color Code: WA121V/GXG Ready to order this paint Select Products Verify your GMC's color code is ' WA121V/GXG ' before ordering.All Product is CNC Machined From 6061-T6 Air Craft Grade Aluminum Billet.Includes Exterior 2 Door Handle Set or 4 Door Handle Set.All product is color matched with Genuine GM OEM paint color and is built to last and to look great on your truck! Made of aircraft grade aluminum billet 6061-T6 and precision machined to fit perfectly on 1500, 2500 or 3500 series trucks. ACDelco GM Original Equipment 19367759 Iridium Metallic (WA121V) Four-In-One Touch-Up Paint Pen, 0.25 Fl Oz (Pack of 2) 479. ![]() Kit includes a special install tool and comes with complete installation directions. There is no need to take the inside doors apart. Buy Touch Up Express Paint for GMC Sierra 121V Iridium Metallic 12oz Aerosol Spray Kit for Car Auto Truck at Amazon. Fits in place of the factory installed door handles to give you a custom look. GMC Sierra & Chevy Silverado Billet Exterior Door Handle Set featuring Tungsten Metallic/Iridium OEM (GXG) paint to match or contrast your Silverado or Sierra truck. Described as whitish-yellow or silvery in color, it just a little less dense than osmium, which is the densest element-22.560 gm/cm3. Available as 2 Pc Handle Set or 4 Pc Handle Set Iridium is a metallic element that is both hard and brittle. ![]() 2/28/2024 0 Comments Nn model ru sets![]() ![]() We additionally find that applying an external magnetic field whilst the system is in the long-range ordered zigzag ground state can induce a phase transition into a quantum SL. While a SL state does show up in this phase diagram, it arises in a setting different from Kitaev’s original SL regime, as it emerges from an interplay of Kitaev physics and geometrically frustrated magnetism. The resulting magnetic phase diagram that we compute as function of longer-range second- and third-neighbor magnetic couplings is very rich, due to the comparable size of the various residual interactions. It is however significantly weaker than in 5 d 5 Ir oxides and even than in 4 d 5 Li 2RhO 3, which points at a rather different balance between the various superexchange processes in the halide and in the oxides. Calculating the magnetic interactions between two adjacent 1/2-pseudospins, we find that the nearest-neighbor (NN) Kitaev exchange K is ferromagnetic (FM), in any of the α-RuCl 3 crystalline structures reported so far. The trigonally distorted environment further gives rise to strong anisotropy of the computed g factors, consistent with experimental observations 20, 27. ![]() Our results for the Ru 3+ 4 d-shell electronic structure show sizable trigonal splitting of the 4 d t 2 g levels and therefore a spin-orbit ground state that significantly deviates from the j eff = 1/2 picture 7. Here we present results of combined quantum chemistry electronic-structure computations and exact-diagonalization (ED) calculations for extended Kitaev-Heisenberg spin Hamiltonians using as starting point for the ED study the magnetic couplings derived at the quantum chemistry level. But also this material orders antiferromagnetically at low temperatures, as the 5 d 5 iridium oxides do, and precisely how close to the idealized Kitaev model α-RuCl 3 is, remains a question to be clarified. Very recent Raman and neutron scattering measurements suggest that the 4 d 5 halide honeycomb system is closer to the Kitaev limit 22, 23. The SL regime is most likely preempted in the iridates by the presence of significant residual Heisenberg-type J couplings, by longer-range spin interactions, or by having crystallographically distinct Ir-Ir bonds with dominant J’s on some of those, if not a combination of these factors 14, 15, 16, 17.Īlso of interest in this context is ruthenium trichloride, RuCl 3, in its honeycomb ( α) crystalline phase 18, 19, 20, 21, 22, 23, 24, 25, 26. In these systems though long-range magnetic order develops at low temperatures, for all known different crystallographic phases 9, 10, 11, 12, 13. The search to realize the Kitaev model of effectively spin-1/2 particles on the honeycomb lattice was centered until recently mainly on honeycomb iridate materials 7, 8 of the type A 2IrO 3, where A is either Na or Li. Its remarkable properties include protection of quantum information and the emergence of Majorana fermions 5, 6. Of particular interest is the Kitaev Hamiltonian on the honeycomb lattice 5, which is a mathematically well-understood two-dimensional model exhibiting various topological SL states. Whereas there is a rich variety of mathematical models that exhibit SL behavior, finding materials in which a quantum SL state is realized is an intensely pursued goal in present day experimental condensed-matter physics 2, 3, 4. Quantum spin liquids (SL’s) are states of matter that cannot be described by the broken symmetries associated with conventional magnetic ground states 1. Our results offer a unified picture on recent magnetic and spectroscopic measurements on this material and open new perspectives on the prospect of realizing quantum spin liquids in d 5 halides and oxides in general. Using exact diagonalization and density-matrix renormalization group techniques for extended Kitaev-Heisenberg spin Hamiltonians, we find indications for a transition from zigzag order to a gapped spin liquid when applying magnetic field. ![]() A ferromagnetic Kitaev coupling is also supported by a detailed analysis of the field-dependent magnetization. From advanced electronic-structure calculations, we find that the Kitaev interaction is ferromagnetic, as in 5 d 5 iridium honeycomb oxides, and indeed defines the largest superexchange energy scale. Here we discuss the promise for spin-liquid behavior in the 4 d 5 honeycomb halide α-RuCl 3. A prominent case is the Kitaev spin liquid, host of remarkable properties such as protection of quantum information and the emergence of Majorana fermions. Large anisotropic exchange in 5 d and 4 d oxides and halides open the door to new types of magnetic ground states and excitations, inconceivable a decade ago. ![]() |
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